128503-59-3

Basic information

• Product Name: methyl 2-O-benzyl-3,4,6-tri-O-methyl-β-D-glucopyranoside
• Synonyms: methyl 2-O-benzyl-3,4,6-tri-O-methyl-β-D-glucopyranoside
• CAS NO: 128503-59-3
• Molecular Weight: 326.39
• Mol File: 128503-59-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: methyl 2-O-benzyl-3,4,6-tri-O-methyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-O-benzyl-3,4,6-tri-O-methyl-β-D-glucopyranoside(128503-59-3)
• EPA Substance Registry System: methyl 2-O-benzyl-3,4,6-tri-O-methyl-β-D-glucopyranoside(128503-59-3)

Safety Data

• Hazardous Substances Data: 128503-59-3(Hazardous Substances Data)

Upstream product

• 128503-74-2 Methyl 2-O-benzyl-3-O-methyl-α-D-mannopyranoside 
• 74-88-4 methyl iodide 
• 15038-69-4 methyl β-D-glucopyranoside 2-benzyl ether 
• 911652-40-9 methyl-(O²-benzyl-O³-methyl-β-D-glucopyranoside) 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 2348-00-7 methyl 3,4,6-tri-O-methyl-β-D-glucopyranoside 
• 128503-60-6 1-O-Acetyl-2-O-benzyl-3,4,6-tri-O-methyl-α-D-mannopyranoside 
• 34327-07-6 3,4,6-tri-O-methyl-D-glucose 

Relevant articles and documents

Hydroxy group acidities of partially protected glycopyranosides

A comprehensive acidity study of carbohydrate hydroxy groups has been carried out. Relative acidities (Ke) were determined spectrophotometrically for partially methylated methyl α-D- glycopyranosides. Apparently, the acidity is strongly affected by intramolecular hydrogen bonding as well as stereochemistry and solvation. By comparison with pKe and pKa values of aliphatic alcohols and polyols the first estimation of the pKa values for partially protected glycopyranosides was obtained. These findings contribute to the understanding of the relative reactivities of carbohydrate hydroxy groups.