128720-55-8Relevant articles and documents
1,3-Asymmetric Induction in the Reaction of Organometallics to β-Hydroxy Ketones and β-Silyloxy Ketones
Ukaji, Yutaka,Kanda, Hiroyasu,Yamamoto, Kouji,Fujisawa, Tamotsu
, p. 597 - 600 (2007/10/02)
High level of 1,3-asymmetric induction was realized in the reaction between β-hydroxy ketones and triisopropoxytitanium reagents to give anti-1,3-diols possessing tertiary alcohols.To the contrary, syn-1,3-diols were obtained by the addition reaction of organometallics to β-t-butyldimethylsilyloxy ketones.