128930-21-2

Basic information

• Product Name: Ytterbium, bis(2-phenyl-1H-indol-1-yl)tetrakis(tetrahydrofuran)-
• CAS NO: 128930-21-2
• Molecular Formula: C44H52N2O4Yb
• Molecular Weight: 845.948
• Mol File: 128930-21-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ytterbium, bis(2-phenyl-1H-indol-1-yl)tetrakis(tetrahydrofuran)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ytterbium, bis(2-phenyl-1H-indol-1-yl)tetrakis(tetrahydrofuran)-(128930-21-2)
• EPA Substance Registry System: Ytterbium, bis(2-phenyl-1H-indol-1-yl)tetrakis(tetrahydrofuran)-(128930-21-2)

Safety Data

• Hazardous Substances Data: 128930-21-2(Hazardous Substances Data)

Upstream product

• 948-65-2 2-phenyl-indole 
• 973-17-1 bis(pentafluorophenyl)mercury(II) 
• 66080-22-6 bis(pentafluorophenyl)ytterbium(II) 

Downstream Products

• 173612-65-2 bis(2-phenylindol-1-yl)(N,N,N',N'-tetramethylethane-1,2-diamine)ytterbium(II) 
• 173612-63-0 bis(1,2-dimethoxyethane)-bis-μ-(2-phenylindol-1-yl)-bis(2-phenylindol-1-yl)diytterbium(II) 
• 173612-64-1 bis(1,2-dimethoxyethane)bis(2-phenylindol-1-yl)ytterbium(II) 
• 174510-10-2 bis(2-phenylindol-1-yl)(tetrahydrofuran)ytterbium(II) 

Relevant articles and documents

Organoamido- and Aryloxo-lanthanoids. I The Preparation and Characterization of Some Lanthanoid(II) Organoamides, and the X-Ray Crystal Structure of cis-Bis(carbazol-9-yl)tetrakis(tetrahydrofuran)europium(II)

Reaction of carbazole (Hcbz) or 2-phenylindole (Hpin) with bis(pentafluorophenyl)-ytterbium or -europium in tetrahydrofuran (thf) gives the complexes M(cbz)2(thf)4 (M = Yb or Eu) or Yb(pin)2(thf)4.From treatment of lanthanoid metals with bis(pentafluorophenyl)mercury and 2-phenylindole, 2,3,4,5-tetraphenylpyrrole (Htpp) or carbazole, the complexes M(pin)2(thf)4 (M = Yb, Eu or Sm), M(tpp)2(thf)3 (M = Yb or Sm) and Yb(cbz)2(thf)4 have been isolated.Desolvation of M(pin)2(thf)4 under vacuum yields Yb(pin)2(thf) and Sm(pin)2(thf)3.Oxidation of Sm(pin)2(thf)4 with Hg(C6H5)2 and 2-phenylindole gives Sm(pin)3(thf).The crystal structure of Eu(cbz)2(thf)4 shows the complex to be monomeric with distorted octahedral stereochemistry for europium, cis-carbazol-9-yl ligands ( 2.559 Angstroem), and longer Eu-O bonds (av. 2.600 Angstroem) trans to N than mutually trans ( 2.553 Angstroem).Other complexes M(NR2)2(thf)n (NR2 = pin, cbz or tpp) are considered to be monomeric with five (n = 3) or six (n = 4) coordination.