128984-82-7

Basic information

• Product Name: (2R,3S,4R,5R)-N-benzyl-5-hydroxy-2,3,4,6-tetrabenzyloxyhexanamide
• Synonyms: (2R,3S,4R,5R)-N-benzyl-5-hydroxy-2,3,4,6-tetrabenzyloxyhexanamide
• CAS NO: 128984-82-7
• Molecular Weight: 645.796
• Mol File: 128984-82-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: (2R,3S,4R,5R)-N-benzyl-5-hydroxy-2,3,4,6-tetrabenzyloxyhexanamide(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,4R,5R)-N-benzyl-5-hydroxy-2,3,4,6-tetrabenzyloxyhexanamide(128984-82-7)
• EPA Substance Registry System: (2R,3S,4R,5R)-N-benzyl-5-hydroxy-2,3,4,6-tetrabenzyloxyhexanamide(128984-82-7)

Safety Data

• Hazardous Substances Data: 128984-82-7(Hazardous Substances Data)

Upstream product

• 225923-18-2 N-Benzyl-2,3,4,6-tetra-O-benzyl-D-xylo-hex-5-ulosonamide 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 
• 100-46-9 benzylamine 

Downstream Products

• 1414930-64-5 (2R,3S,4R,5R)-N-benzyl-2,3,4,6-tetrabenzyloxy-5-triethylsiloxyhexanamide 
• 1414930-68-9 C₅₂H₆₅NO₈Si 
• 1414930-59-8 (2R,3S,4R,5R)-N-{(S)-1-allyloxycarbonyl-2-phenylethyl}-2,3,4,6-tetrabenzyloxy-5-{(S)-2-tertbutoxycarbonamidopropionyloxy}hexanamide 
• 1414930-72-5 (2R,3S,4R,5R)-N-{(S)-1-ethoxycarbonyl-2-phenylethyl}-2,3,4,6-tetrabenzyloxy-5-triethylsiloxyhexanamide 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 
• 13096-63-4 2,3,4,6-Tetra-O-benzyl-N,N-dimethyl-D-gluconamid 
• 225923-18-2 N-Benzyl-2,3,4,6-tetra-O-benzyl-D-xylo-hex-5-ulosonamide 

Relevant articles and documents

Synthesis of glycosylamines and glyconamides using molecular iodine

We describe herein the synthesis of glyconamides and glycosylamines usingmolecular iodine on benzylated carbohydrates. During the improvement and the optimization of the direct oxidative amidation reaction,we also discovered the possibility to form glycosylamines with excellent yields and short reaction times in comparison with the previously reported procedures. Advantages of these methods are the operational simplicity, elimination of use of complicated reagents and procedures, and generality of the reactions. Our methodology is an excellent access to precursors of N-alkyliminosugars and imino-C-glycosides.

Metal-free one-pot oxidative amidation of aldoses with functionalized amines

(Chemical Equation Presented) Metal-free one-pot oxidative amidation of aldoses with functionalized amines using iodine provides a rapid access to functionalized aldonamides. The main advantage of this approach relies on the fact that aldehyde oxidation and C-N bond formation are performed in a single synthetic operation.

Some comments on an allegedly "facile synthesis of nojirimycin"

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