1290130-76-5

Basic information

• Product Name: C₁₄H₁₅NO₅
• Synonyms: C₁₄H₁₅NO₅
• CAS NO: 1290130-76-5
• Molecular Weight: 277.277
• Mol File: 1290130-76-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: C₁₄H₁₅NO₅(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₄H₁₅NO₅(1290130-76-5)
• EPA Substance Registry System: C₁₄H₁₅NO₅(1290130-76-5)

Safety Data

• Hazardous Substances Data: 1290130-76-5(Hazardous Substances Data)

Upstream product

• 800379-17-3 (3aR,5S,6R,6aR)-6-azido-2,2-dimethyltetrahydrofuro[2,3-d][1,3]-dioxole-5-carboxylic acid 
• 107690-61-9 3,6-epimino-3,5,6-trideoxy-1,2-O-isopropylidene-α-D-xylo-hexofuranose 
• 28072-61-9 3-azido-3-deoxy-1,2-O-isopropylidene-α-D-xylo-pentodialdo-1,4-furanose 
• 98944-20-8 (1R,3R,7R,8S)-9-<(benzyloxy)carbonyl>-5,5-dimethyl-2,4,6-trioxa-9-azatricyclo<6.3.0.0^3,7>undecane 

Downstream Products

• 1262015-07-5 (2S,3R)-N-(benzyloxycarbonyl)-3-hydroxypyrrolidine-2-carboxylic acid 
• 133161-12-3 (2R,3R)-1-(Benzyloxycarbonyl)-3-hydroxy-2-(hydroxymethyl)pyrrolidine 
• 198625-17-1 (R,R)-3-hydroxy-2-hydroxymethylpyrrolidine 

Relevant articles and documents

D-Glucose based syntheses of β-hydroxy derivatives of l-glutamic acid, l-glutamine, l-proline and a dihydroxy pyrrolidine alkaloid

The β-hydroxy derivatives of l-glutamic acid, l-glutamine and l-proline, useful for peptide/protein studies, were synthesized starting from d-glucose. The C2 carbon in d-glucose provided the carboxylic acid functionality, while the amino and β-hydroxy groups of the amino acids were amenable from the C3 and C4 hydroxy groups of the sugar, respectively. The key intermediate with appropriate carbon framework of the target molecules was constructed by homologation of a suitable azido-d-glucofuranose derivative using the Arndt-Eistert reaction. This journal is