129135-32-6

Basic information

• Product Name: 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene
• Synonyms: 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene
• CAS NO: 129135-32-6
• Molecular Weight: 604.794
• Mol File: 129135-32-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene(CAS DataBase Reference)
• NIST Chemistry Reference: 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene(129135-32-6)
• EPA Substance Registry System: 6-benzyl-3,9-ditosyl-3,6,9,15-tetraazabicyclo[9,3,1]pentadeca-1⁽¹⁵⁾,11,13-triene(129135-32-6)

Safety Data

• Hazardous Substances Data: 129135-32-6(Hazardous Substances Data)

Upstream product

• 1195-59-1 2.6-bis(hydroxymethyl)pyridine 
• 98-59-9 p-toluenesulfonyl chloride 
• 3634-89-7 N-(p-toluenesulfonyl)aziridine 
• 6367-75-5 2-(tosylamino)ethyl p-toluenesulfonate 
• 3099-28-3 2,6-bis(chloromethyl)pyridine 
• 112193-79-0 N³-benzyl-N¹,N⁵-ditosyl-3-aza-1,5-pentanediamine 

Downstream Products

• 1588866-18-5 C₃₂H₃₆AgN₄O₄S₂⁽¹⁺⁾*CF₃O₃S^(1-) 
• 1588866-19-6 C₃₂H₃₆AgN₄O₄S₂⁽¹⁺⁾*C₂F₆NO₄S₂^(1-) 
• 1345011-90-6 C₃₂H₃₆CuN₄O₄S₂⁽¹⁺⁾*CF₃O₃S^(1-) 
• 1422017-43-3 C₃₂H₃₆N₄O₄S₂*CHF₃O₃S 

Relevant articles and documents

Mild regiospecific synthesis of 1-alkoxy-isochromenes catalyzed by well-defined [silver(I)(pyridine-containing ligand)] complexes

The synthesis of 3-substituted-1-alkoxyisochromenes starting from 2-alkynylbenzaldehydes and different alcohols is reported. The reaction is catalyzed by a silver(I) complex with an original macrocyclic pyridine-containing ligand. The approach is characterized by absolute regioselectivity, mild reaction conditions, good to excellent reaction yields, cleanness of the reaction, and reduced purification steps. The reaction mechanism was investigated by in-depth 1H NMR experiments and an aimed trapping experiment.