1293-87-4 Usage
Description
1,1'-FERROCENEDICARBOXYLIC ACID is an organic compound with the chemical formula C11H10FeO4. It is a dark brown powder and is known for its unique chemical properties and potential applications in various fields.
Uses
Used in Chemical Synthesis:
1,1'-FERROCENEDICARBOXYLIC ACID is used as a reactant for the preparation of planar chiral ferrocene-based amido-phosphine ligands, which serve as catalysts for asymmetric allylic alkylation reactions. This application is crucial in the synthesis of complex organic molecules with specific stereochemistry.
Used in Pharmaceutical Industry:
1,1'-FERROCENEDICARBOXYLIC ACID is considered as a potential antitumor agent due to its unique chemical structure and properties. It may be further investigated and developed for use in cancer treatment.
Used in Material Science:
1,1'-FERROCENEDICARBOXYLIC ACID is used in the development of isostructural ferrocenyl coordination polymer hollow microspheres. These materials exhibit H2 storage properties, making them potentially useful in the field of energy storage and hydrogen fuel applications.
Used in Polymer Chemistry:
1,1'-FERROCENEDICARBOXYLIC ACID is utilized in the synthesis of organometallic aromatic polyesters, which are materials with potential applications in various industries, including plastics, coatings, and adhesives.
Used in Coordination Chemistry:
1,1'-FERROCENEDICARBOXYLIC ACID is used in the formation of manganese-lanthanide-ferrocene clusters. These clusters have potential applications in various fields, such as catalysis, magnetism, and electronics, due to their unique properties and structures.
Purification Methods
It crystallises in orange-yellow crystals from AcOH and sublimes above 230o. The monomethyl ester has m 147-149o [Nesmeyanov & Reutov Dokl Acad Nauk USSS 115 518 1957]. The dimethyl ester has m 114-115o [Woodward et al. J Am Chem Soc 74, 3458 1953]. The diacid chloride has m 92-93o when recrystallised from pet ether. [Nesmeyanov & Reutov Dokl Acad Nauk SSSR 120 1267 1958, Kazitsyna et al. Dokl Acad Nauk SSSR 127 333 1959, Beilstein 16 IV 1811.]
Check Digit Verification of cas no
The CAS Registry Mumber 1293-87-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,2,9 and 3 respectively; the second part has 2 digits, 8 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 1293-87:
(6*1)+(5*2)+(4*9)+(3*3)+(2*8)+(1*7)=84
84 % 10 = 4
So 1293-87-4 is a valid CAS Registry Number.
1293-87-4Relevant articles and documents
A solid-gas route to polymorph conversion in crystalline [Fe II(η5-C5H4COOH)2]. A diffraction and solid-state NMR study
Braga, Dario,Grepioni, Fabrizia,Polito, Marco,Chierotti, Michele R.,Ellena, Silvano,Gobetto, Roberto
, p. 4627 - 4633 (2008/10/09)
Crystalline form I (monoclinic) and form II (triclinic) of ferrocene dicarboxylic acid [Fe(η5-C5H4-COOH) 2] have been employed in solid-gas reactions at room temperature with the gaseous bases NH3, NH2(CH3), and NH(CH3)2. The two crystal forms behave in exactly the same way in the solid-gas reaction, generating the same products, identified as the anhydrous crystalline salts [NH4]2-[Fe(η5- C5H4-COO)2] (1), [NH3CH 3]2[Fe(η5-C5H 4COO)2] (2), and [NH2(CH3) 2]2[Fe(η5-C5H 4COO)2] (3). Interestingly though, all these crystals revert via vapor release exclusively to the metastable crystalline form I. Starting materials and products have been investigated by single-crystal and powder diffraction and by 13C, 15N CPMAS and 1H MAS methods.