129503-55-5Relevant articles and documents
Reactions of Sulfoxides Bearing ortho-Sulfur Functional Groups and Thianthrene Monoxide with Grignard Reagents
Furukawa, Naomichi,Ogawa, Satoshi,Matsumura, Kazunori,Shibutani, Tadao,Fujihara, Hisashi
, p. 979 - 982 (2007/10/02)
Diaryl sulfoxides bearing ortho-sulfur substituents react readily with Grignard reagents on the sulfur atom to produce the corresponding phenyl Grignard reagents bearing ortho-sulfur functional group.Furthermore, thianthrene monooxide was found to react with alkyl Grignard reagents affording o,o'-bis-Grignard reagent of diphenyl sulfide which was converted easily to Martin's sulfurane.