129512-44-3

Basic information

• Product Name: tert-butyldimethylsilyl 2-acetoxybenzoate
• Synonyms: tert-butyldimethylsilyl 2-acetoxybenzoate
• CAS NO: 129512-44-3
• Molecular Weight: 294.423
• Mol File: 129512-44-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: tert-butyldimethylsilyl 2-acetoxybenzoate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyldimethylsilyl 2-acetoxybenzoate(129512-44-3)
• EPA Substance Registry System: tert-butyldimethylsilyl 2-acetoxybenzoate(129512-44-3)

Safety Data

• Hazardous Substances Data: 129512-44-3(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 41879-37-2 t-butyldimethylsilyl amine 
• 50-78-2 aspirin 
• 129512-40-9 3-(tert-butyldimethylsilyloxy)-2-methylbenzofuran 

Downstream Products

• 4143-74-2 4'-methoxyflavone 
• 5751-48-4 2-methylchromone 

Relevant articles and documents

Tert-Butyldimethylsilyl Amine (TBDMS-NH2): A Mild and Green Reagent for the Protection of Benzyl Alcohols, Phenols, and Carboxylic Acids under Solvent-Free Conditions

Herein, we present the use of the tert-butyldimethylsilyl amine (TBDMS-NH2) as a silylating reagent for phenols, benzyl alcohols, and carboxylic acids. Unlike other silyl protection reactions, this reported process with TBDMS-NH2 does not involve the form

Photooxygenation of 3- and 2-silyloxybenzofurans: Rearrangement of dioxetanes via α-silylperoxy ketones to ketoester cleavage products

Photooxygenation of 2-methyl-3-silyloxybenzofurans 1 afforded isolable dioxetranes 2, the latter rearranged via α-silylperoxy ketones 3 to cleavage products 4; 2-silyloxy-3-methylbenzofuran 6 with 1O2 gave the more stable dioxetane 7.