129648-68-6Relevant articles and documents
Transition-state stabilization and molecular recognition: Acceleration of phosphoryl-transfer reactions by an artificial receptor
Tecilla, Paolo,Chang, Suk-Kyu,Hamilton, Andrew D.
, p. 9586 - 9590 (1990)
An artificial receptor that is complementary to the proposed trigonal-bipyramidal intermediate for phosphoryl-transfer reactions has been designed. Kinetic measurements with 31P NMR methods show that the receptor causes up to a 10-fold acceleration in the aminolysis of phosphorodiamidic chloride derivatives, proceeding via an associative mechanism.
Determination of binding constants of hydrogen-bonded complexes by ITC, NMR CIS, and NMR diffusion experiments
Dethlefs, Christiane,Eckelmann, Jens,Kobarg, Hauke,Weyrich, Thomas,Brammer, Stefan,Naether, Christian,Luening, Ulrich
, p. 2066 - 2074 (2011/05/16)
The host-guest complex formation between barbital and various acylaminopyridyl isophthalamides (Hamilton receptors) has been determined quantitatively. The syntheses of nine isophthalamides are described. Their structures differ in the substitution patter