129801-20-3

Basic information

• Product Name: N-(1-methoxycarbonyl-2,2,2-trifluoroethylidene)-α-methylbenzylamine
• Synonyms: N-(1-methoxycarbonyl-2,2,2-trifluoroethylidene)-α-methylbenzylamine
• CAS NO: 129801-20-3
• Molecular Weight: 259.228
• Mol File: 129801-20-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(1-methoxycarbonyl-2,2,2-trifluoroethylidene)-α-methylbenzylamine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(1-methoxycarbonyl-2,2,2-trifluoroethylidene)-α-methylbenzylamine(129801-20-3)
• EPA Substance Registry System: N-(1-methoxycarbonyl-2,2,2-trifluoroethylidene)-α-methylbenzylamine(129801-20-3)

Safety Data

• Hazardous Substances Data: 129801-20-3(Hazardous Substances Data)

Upstream product

• 13089-11-7 methyl 3,3,3-trifluoropyruvate 
• 618-36-0 rac-methylbenzylamine 

Downstream Products

• 119887-07-9 N-(1-phenylethyl)-3,3,3-trifluoroalanine methyl ester hydrochloride 
• 119866-80-7 3,3,3-Trifluoro-2-(1-phenyl-ethylamino)-propionic acid methyl ester 
• 129801-21-4 methyl ester of N-(α-methylbenzylidene)-3,3,3-trifluoroalanine 

Relevant articles and documents

FLUORINE-CONTAINING AMINO ACIDS. V. IMINES OF TRIFLUOROPYRUVIC ACID IN THE SYNTHESIS OF N-SUBSTITUTED TRIFLUOROALANINES

N-Substituted trifluoroalanine methyl esters were obtained by the reduction of the corresponding imines of trifluoropyruvic acid with zinc in acetic acid.The N-butyl- and N-(1-phenylethyl)imines undergo a -proton shift under the influence of bases with the formation of trifluoroalanine derivatives.It was found that the N-(1-phenylethyl)imine of tetrafluoropyruvic acid is formed directly from the corresponding amine and methyl trifluoropyruvate under conditions with azeotropic distillation of the water with toluene in the presence of acidic catalysis.