1298134-92-5

Basic information

• Product Name: dipyrimidin-5-ylamine
• CAS NO: 1298134-92-5
• Molecular Weight: 173.177
• Mol File: 1298134-92-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dipyrimidin-5-ylamine(CAS DataBase Reference)
• NIST Chemistry Reference: dipyrimidin-5-ylamine(1298134-92-5)
• EPA Substance Registry System: dipyrimidin-5-ylamine(1298134-92-5)

Safety Data

• Hazardous Substances Data: 1298134-92-5(Hazardous Substances Data)

Upstream product

• 4595-59-9 5-bromopyrimidine 

Relevant articles and documents

Selective Cross-Coupling of (Hetero)aryl Halides with Ammonia to Produce Primary Arylamines using Pd-NHC Complexes

Herein we report the first example of (hetero)arylation of ammonia using a monoligated palladium-NHC complex. The new, rationally designed, precatalyst (DiMeIHeptCl)Pd(allyl)Cl featuring highly branched alkyl chains has been shown to be effective in selective aminations across a range of challenging substrates, including nitrogen-containing heterocycles and those featuring base-sensitive functionality. The less bulky Pd-PEPPSI-IPentCl precatalyst performs well for ortho-substituted aryl halides, giving monoarylated products in high yield with good selectivity.