129880-59-7

Basic information

• Product Name: Benzenamine, N,N-bis[(diphenylphosphino)methyl]-
• CAS NO: 129880-59-7
• Molecular Formula: C32H29NP2
• Molecular Weight: 489.536
• Mol File: 129880-59-7.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzenamine, N,N-bis[(diphenylphosphino)methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, N,N-bis[(diphenylphosphino)methyl]-(129880-59-7)
• EPA Substance Registry System: Benzenamine, N,N-bis[(diphenylphosphino)methyl]-(129880-59-7)

Safety Data

• Hazardous Substances Data: 129880-59-7(Hazardous Substances Data)

Upstream product

• 62-53-3 aniline 
• 5958-44-1 diphenylphosphinomethanol 
• 1401420-41-4 N,N-bis(diphenylphosphinoylmethyl)aniline 
• 4559-70-0 Diphenylphosphine oxide 
• 829-85-6 diphenylphosphane 
• 50-00-0 formaldehyd 

Downstream Products

• 1122502-54-8 PhN(CH₂PPh₂)₂NiCl₂ 
• 1316861-41-2 [Cu(2,9-dimethyl-1,10-phenanthroline)(N,N-bis((diphenylphosphino)methyl)benzenamine)][B(fluoride)4] 
• 1316861-32-1 [Cu(1,10-phenanthroline)(N,N-bis((diphenylphosphino)methyl)benzenamine)][B(fluoride)4] 
• 1401420-45-8 cis-[bis(diphenylphosphinomethyl)aniline]dichloroplatinum(II) 
• 1333203-69-2 [(N,N-bis((diphenylphosphino)methyl)phenylamine)NiI]I 
• 1333203-68-1 [(N,N-bis((diphenylphosphino)methyl)phenylamine)CoI₂] 
• 1250872-02-6 Mn(Ph₂PCH₂N(Ph)CH₂PPh₂)(CO)3(Br) 
• 1201830-12-7 [{Fe₂(μ-1,3-propanedithiolate)(CO)₅}₂(μ, κ¹, κ¹-Ph₂PCH₂N(Ph)CH₂PPh₂)] 
• 449145-17-9 ReBr(CO)3(((C₆H₅)2PCH₂)2NC₆H₅) 

Relevant articles and documents

New functionalised ditertiary phosphines via phosphorus based Mannich condensation reactions

The one-step synthesis of a family of functionalised ditertiary aminophosphines are described including the X-ray crystal structure of 4-{(Ph2PCH2)2N}C6H4CO 2H.

Catalyst Pendent-Base Effects on Cyclization of Alkynyl Amines

A family of [CpRu(PP)(MeCN)]PF6 complexes (2 a–e and 4) were prepared in which the bis-phosphine ligand contains a pendent tertiary amine in the second-coordination sphere. 2 a–e contain PPh2NR′2 ligands with two amine groups as the pendent base. Complex 4 has the PPh2NPh1 ligand with only one pendent amine. The catalytic performance of 2 a–e and 4 were assessed in the cyclization of 2-ethynyl aniline and 2-ethynylbenzyl alcohol. It was revealed that the positioning of the pendent amine near the metal active site is essential for high catalyst performance. A comparison of PPh2NR′2 catalysts (2 a–e) showed minimal difference in performance as a function of pendent amine basicity. Rather, only a threshold basicity – in which the pendent amine was more basic than the substrate – was required for high performance.

Microwave-assisted synthesis of organophosphorus compounds

Kabachnik-Fields reactions of a variety of amines, phospha-Michael additions to maleimide derivatives and alcoholysis of dialkyl phosphites were studied under microwave conditions.