129958-40-3

Basic information

• Product Name: N-(4-methyl-3-nitrobenzenesulfonyl)-1,3,3-trimethylcyclobutanecarboximidate
• Synonyms: N-(4-methyl-3-nitrobenzenesulfonyl)-1,3,3-trimethylcyclobutanecarboximidate
• CAS NO: 129958-40-3
• Molecular Weight: 354.427
• Mol File: 129958-40-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(4-methyl-3-nitrobenzenesulfonyl)-1,3,3-trimethylcyclobutanecarboximidate(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-methyl-3-nitrobenzenesulfonyl)-1,3,3-trimethylcyclobutanecarboximidate(129958-40-3)
• EPA Substance Registry System: N-(4-methyl-3-nitrobenzenesulfonyl)-1,3,3-trimethylcyclobutanecarboximidate(129958-40-3)

Safety Data

• Hazardous Substances Data: 129958-40-3(Hazardous Substances Data)

Upstream product

• 4694-12-6 2,4,4-trimethylcyclopentan-1-one 
• 120893-18-7 4-methyl-3-nitrobenzenesulfonyl azide 
• 149-73-5 trimethyl orthoformate 

Relevant articles and documents

REACTION OF ORGANIC AZIDES WITH UNSATURATED COMPOUNDS XI. REARRANGEMENTS OF BICYCLIC TRIAZOLINES, OBTAINED FROM TAUTOMERIC 2,4,4-TRIMETHYL-AND 3,3,5-TRIMETHYL-1-METHOXYCYCLOPENTENES AND 4-METHYL-3-NITROBENZENESULFONYL AZIDE

The reaction of 4-methyl-3-nitrobenzenesulfonyl azide with the tautomeric 2,4,4-trimethyl- and 3,3,5-trimethyl-1-methoxycyclopentenes leads to the formation of the products from transformation of both triazolines in almost equal ratios.The less substituted triazoline is converted through the corresponding aziridine into the allylsulfonamide, while the more substituted triazoline rearranges preferentially to methyl N-arylsulfonyl-1,3,3-trimethylcyclobutanecarboximidate.