1301127-15-0

Basic information

• Product Name: (E)-(2-nitrohex-1-en-1-yl)benzene
• Synonyms: (E)-(2-nitrohex-1-en-1-yl)benzene
• CAS NO: 1301127-15-0
• Molecular Weight: 205.257
• Mol File: 1301127-15-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-(2-nitrohex-1-en-1-yl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(2-nitrohex-1-en-1-yl)benzene(1301127-15-0)
• EPA Substance Registry System: (E)-(2-nitrohex-1-en-1-yl)benzene(1301127-15-0)

Safety Data

• Hazardous Substances Data: 1301127-15-0(Hazardous Substances Data)

Upstream product

• 628-05-7 1-nitropentane 
• 100-52-7 benzaldehyde 

Downstream Products

• 10264-05-8 pentanoic acid benzylamide 

Relevant articles and documents

Dynamic kinetic asymmetric ring-opening/reductive amination sequence of racemic nitroepoxides with chiral amines: Enantioselective synthesis of chiral vicinal diamines

We report a highly diastereoselective synthesis of vicinal diamines by the treatment of nitroepoxides with primary amines and then a reducing agent. When using a chiral primary amine, racemic nitroepoxides are transformed into chiral diamines as a single enantiomers (>95:5 er) through a dynamic kinetic asymmetric transformation (DYKAT). The overall process is a one-pot procedure combining the exposure of nitroepoxides to chiral amines to afford diastereomeric mixtures of aminoimines and subsequent stereoselective imine reduction.