130136-57-1Relevant articles and documents
REACTION OF NITRO COMPOUNDS TOWARDS GRIGNARD REAGENTS. A GENERAL METHOD OF SYNTHESIS OF N-ALKYL- OR N-ARYL-N-PROPARGYLHYDROXYLAMINES
Bartoli, Giuseppe,Palmieri, Gianini,Petrini, Marino,Bosco, Marcella,Dalpozzo, Renato
, p. 247 - 249 (2007/10/02)
The reaction between nitro compounds and the Grignard reagent derived from propargyl bromide and magnesium leads to a prevalent 1,2-adduct which can be reduced to the corresponding hydroxylamino derivative by LiAlH4 and 10percent Pd/C.The reaction can be