130255-49-1Relevant articles and documents
A facile synthesis of 1,1-bis(silyl)ethenes
Pawluc, Piotr,Marciniec, Bogdan,Hreczycho, Grzegorz,Gaczewska, Beata,Itami, Yujiro
, p. 370 - 372 (2005)
(Chemical Equation Presented). Symmetrical 1,1-bis(silyl)ethenes have been easily prepared via ruthenium complex-catalyzed silylative coupling cyclization of 1,2-bis(dimethylvinylsiloxy)ethane to give 2,2,4,4-tetramethyl-3-methylene-1, 5-dioxa-2,4-disilac
Phosphine-stabilized, oxide-supported rhodium catalysts for highly efficient silylative coupling reactions
Tsukada, Shinji,Wada, Kenji,Miura, Hiroki,Hosokawa, Saburo,Abe, Ryu,Inoue, Masashi
, p. 9575 - 9586 (2016/01/12)
Oxide-supported rhodium catalysts with excellent activity in silylative coupling reactions have been developed. Reductive pretreatment of the catalysts in the presence of 0.5 equiv triphenylphosphine under a hydrogen atmosphere enhanced and stabilized the
Shuffle off the classic β-Si elimination by Ni-NHC cooperation: Implication for C-C forming reactions involving Ni-alkyl-β-silanes
Ho, Chun-Yu,He, Lisi
supporting information; experimental part, p. 1481 - 1483 (2012/03/11)
Via a cooperation of NHC, Si substituents and a M center, β-Si elimination was attenuated, revealing a new way to attain a high Ni-β-SiR3:Ni-σ-SiR3 ratio. The scope is illustrated by a head-to-tail vinylsilane-α-olefin hydroalkenylation.