130264-65-2

Basic information

• Product Name: Acetic acid (3R,3aS,4R,5R,6R,7aS)-6-acetoxymethyl-4-bromo-3-(toluene-4-sulfonylmethyl)-hexahydro-furo[2,3-b]pyran-5-yl ester
• CAS NO: 130264-65-2
• Molecular Weight: 505.384
• Mol File: 130264-65-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Acetic acid (3R,3aS,4R,5R,6R,7aS)-6-acetoxymethyl-4-bromo-3-(toluene-4-sulfonylmethyl)-hexahydro-furo[2,3-b]pyran-5-yl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid (3R,3aS,4R,5R,6R,7aS)-6-acetoxymethyl-4-bromo-3-(toluene-4-sulfonylmethyl)-hexahydro-furo[2,3-b]pyran-5-yl ester(130264-65-2)
• EPA Substance Registry System: Acetic acid (3R,3aS,4R,5R,6R,7aS)-6-acetoxymethyl-4-bromo-3-(toluene-4-sulfonylmethyl)-hexahydro-furo[2,3-b]pyran-5-yl ester(130264-65-2)

Safety Data

• Hazardous Substances Data: 130264-65-2(Hazardous Substances Data)

Upstream product

• 1950-69-2 toluene-p-sulfonyl bromide 
• 121703-30-8 prop-2-enyl 4,6-di-O-acetyl-2,3-dideoxy-α-D-erythrohex-2-enopyranoside 

Relevant articles and documents

Stereoselective Free-Radical Cyclization on a Sugar Template The Suphonyl Radical as a Synthetic Tool for Functionalized Glycosides

The addition of a sulphonyl radical to the external double bond of an allyl glycal generates a pro-chiral carbon radical which adds to the glycal double bond with a high diastereoselectivity.Through three consecutive radical steps, the configurations of three new asymmetric centers are controlled.