130633-41-9

Basic information

• Product Name: Z-Met-Met-OEt
• CAS NO: 130633-41-9
• Molecular Weight: 442.601
• Mol File: 130633-41-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Z-Met-Met-OEt(CAS DataBase Reference)
• NIST Chemistry Reference: Z-Met-Met-OEt(130633-41-9)
• EPA Substance Registry System: Z-Met-Met-OEt(130633-41-9)

Safety Data

• Hazardous Substances Data: 130633-41-9(Hazardous Substances Data)

Upstream product

• 501-53-1 benzyl chloroformate 
• 63-68-3 L-methionine 
• 2899-36-7 L-methionine ethyl ester monohydrochloride 
• 84889-07-6 (S)-2-Benzyloxycarbonylamino-4-methylsulfanyl-butyric acid; compound with dicyclohexyl-amine 

Relevant articles and documents

KINETICS OF THE ALKALINE HYDROLYSIS OF SEVERAL N-BENZYLOXYCARBONYLDIPEPTIDE METHYL AND ETHYL ESTERS

The reaction rates of the alkaline hydrolysis of synthesized N-protected dipeptide methyl and ethyl esters were studied systematically.From the kinetic data the energies of activation, the pre-exponential factors and the reference values at 40 deg C were calculated.The rate of hydrolysis shows to be strongly dependent on the C-terminal amino acid in the sequence Gly >> Ala/Met/Phe > Leu >> Val/Pro.Surprisingly the N-terminal amino acid also exerts an effect, but in a different sequence.N-Terminal Phe in particular shows a relative accelerating effect.Remarkable is the significantly faster ester hydrolysis of glycine containing dipeptide ethyl esters in ethanol/water compared to the corresponding methyl esters in methanol/water.