130690-84-5

Basic information

• Product Name: (3S,4R)-4-Chloro-3-methyl-3-p-tolyl-5,5-bis-trimethylsilanyl-4,5-dihydro-3H-[1,2,4]diazaphosphole
• CAS NO: 130690-84-5
• Molecular Weight: 371.009
• Mol File: 130690-84-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,4R)-4-Chloro-3-methyl-3-p-tolyl-5,5-bis-trimethylsilanyl-4,5-dihydro-3H-[1,2,4]diazaphosphole(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4R)-4-Chloro-3-methyl-3-p-tolyl-5,5-bis-trimethylsilanyl-4,5-dihydro-3H-[1,2,4]diazaphosphole(130690-84-5)
• EPA Substance Registry System: (3S,4R)-4-Chloro-3-methyl-3-p-tolyl-5,5-bis-trimethylsilanyl-4,5-dihydro-3H-[1,2,4]diazaphosphole(130690-84-5)

Safety Data

• Hazardous Substances Data: 130690-84-5(Hazardous Substances Data)

Upstream product

• 79454-85-6 [bis(trimethylsilyl)methylene]chlorophosphane 
• 64252-52-4 1-(1-diazoethyl)-4-methylbenzene 
• 5926-35-2 chlorobis(trimethylsilyl)methane 
• 15951-41-4 bis(trimethylsilyl)dichloromethane 
• 64252-53-5 4-methylacetophenone hydrazone 
• 76505-20-9 bis(trimethylsilyl)methyldichlorophosphine 
• 122-00-9 para-methylacetophenone 

Relevant articles and documents

CYCLOADDITIONS OF DISUBSTITUTED DIAZO COMPOUNDS TO P-CHLORO(BISTRIMETHYLSILYL) METHYLENE PHOSPHINE.

Disubstituted diazo compounds rapidly add to P-chloro (bistrimethylsilyl) methylene phosphine at low temperature. 1H, 31P and 13C NMR allow the characterization of the resulting cycloadducts and the establisment of the stereochemistry of the resulting cycloadducts which are potential precursors of ?3λ5 bis methylene phosphorane by nitrogen extrusion.