130716-96-0Relevant articles and documents
ORIENTATION IN THE NUCLEOPHILIC ATTACK OF ISOBUTYRONITRILE ANION ON (η6-BENZYL ALCOHOL)TRICARBONYLCHROMIUM(0) COMPLEXES
Camps, Francisco,Coll, Josep,Moreto, Josep M.,Pages, Lluis,Roget, Joan
, p. 1824 - 1835 (2007/10/02)
The reactivity of tricarbonyl chromium seven methoxybenzyl alcohols in the lithioisobutyronitrile was compared with that of benzyl alcohol complex.In all cases, the at nucleophile showed a clear regioselectivity for para and meta to the hydroxymethyl substituent.Kj might be operating in most cases, the expected p those arising mainly from charge control.