130727-55-8Relevant articles and documents
Extended Open-Chain Polyenides as Versatile Delocalized Anion Ligands for Metal Chain Clusters
Yamashita, Mitsuki,Kawasumi, Yuna,Tachibana, Yuki,Horiuchi, Shinnosuke,Yamamoto, Koji,Murahashi, Tetsuro
, p. 1212 - 1216 (2019)
Although small cyclic- and open-chain unsaturated hydrocarbon anions such as cyclopentadienide and open-chain pentadienide are used as the strongly electron-donating auxiliary ligands for metal complexes, more extended π-conjugated unsaturated hydrocarbon
How far can a carbanion delocalize? 13C NMR studies on soliton model compounds
Tolbert, Laren M.,Ogle, Mark E.
, p. 9519 - 9527 (2007/10/02)
For well-defined π systems, 13C chemical shifts are correlated with π-electron density. We have used this correlation to develop models for charge carriers in n-doped polyacetylene ("solitons") that allow us to determine if the charge density d