1309382-38-4

Basic information

• Product Name: 1,6-anhydro-2-O-(4-bromobenzyl)-β-D-mannopyranoside
• Synonyms: 1,6-anhydro-2-O-(4-bromobenzyl)-β-D-mannopyranoside
• CAS NO: 1309382-38-4
• Molecular Weight: 331.163
• Mol File: 1309382-38-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,6-anhydro-2-O-(4-bromobenzyl)-β-D-mannopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6-anhydro-2-O-(4-bromobenzyl)-β-D-mannopyranoside(1309382-38-4)
• EPA Substance Registry System: 1,6-anhydro-2-O-(4-bromobenzyl)-β-D-mannopyranoside(1309382-38-4)

Safety Data

• Hazardous Substances Data: 1309382-38-4(Hazardous Substances Data)

Upstream product

• 589-15-1 1-bromomethyl-4-bromobenzene 
• 14168-65-1 mannosan 

Relevant articles and documents

Regioselective alkylation of carbohydrate derivatives catalyzed by a diarylborinic acid derivative

Regioselective, catalyst-controlled monoalkylations of cis-vicinal diol motifs in carbohydrate derivatives, using a diphenylborinic ester precatalyst, are described. Selective installation of benzyl, naphthylmethyl, 4-bromobenzyl and benzyloxymethyl protective groups at a single secondary hydroxy group of ten representative carbohydrate derivatives illustrates the scope of this method. This new mode of catalytic reactivity represents an operationally simple method to access useful monoalkylated building blocks while avoiding the use of stoichiometric quantities of organotin reagents.