1309385-87-2

Basic information

• Product Name: 2-(3-(tert-butyl)phenyl)-1,3-dioxolane
• Synonyms: 2-(3-(tert-butyl)phenyl)-1,3-dioxolane
• CAS NO: 1309385-87-2
• Molecular Weight: 206.285
• Mol File: 1309385-87-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-(3-(tert-butyl)phenyl)-1,3-dioxolane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(3-(tert-butyl)phenyl)-1,3-dioxolane(1309385-87-2)
• EPA Substance Registry System: 2-(3-(tert-butyl)phenyl)-1,3-dioxolane(1309385-87-2)

Safety Data

• Hazardous Substances Data: 1309385-87-2(Hazardous Substances Data)

Upstream product

• 17789-14-9 3-(1,3-dioxolan-2-yl)-phenylbromide 
• 677-22-5 tert-butylmagnesium chloride 

Relevant articles and documents

Nickel-catalyzed Kumada cross-coupling reactions of tertiary alkylmagnesium halides and aryl bromides/triflates

We report a Ni-catalyzed process for the cross-coupling of tertiary alkyl nucleophiles and aryl bromides. This process is extremely general for a wide range of electrophiles and generally occurs with a ratio of retention to isomerization >30:1. The same procedure also accommodates the use of aryl triflates, vinyl chlorides, and vinyl bromides as the electrophilic component.