130947-28-3

Basic information

• Product Name: trans-<β-2H>cinnamaldehyde
• Synonyms: trans-<β-2H>cinnamaldehyde
• CAS NO: 130947-28-3
• Molecular Weight: 133.154
• Mol File: 130947-28-3.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: trans-<β-2H>cinnamaldehyde(CAS DataBase Reference)
• NIST Chemistry Reference: trans-<β-2H>cinnamaldehyde(130947-28-3)
• EPA Substance Registry System: trans-<β-2H>cinnamaldehyde(130947-28-3)

Safety Data

• Hazardous Substances Data: 130947-28-3(Hazardous Substances Data)

Upstream product

• 2568-57-2 N-(3-phenyl-2-propynyl)piperidine 
• 101905-63-9 (E)-1-(benzo[d][1,3]dioxol-6-yl)-3-(dimethyl(phenyl)silyl)prop-2-en-1-ol 
• 23094-22-6 3,3-dideutero-3-phenylpropionic acid 
• 29372-34-7 3-phenylpropanal-3,3-d₂ 
• 3592-47-0 Benzaldehyde-d 
• 87482-94-8 CO₂C₂H₅C₂H⁽²⁾HC₆H₅ 
• 63523-01-3 3-phenyl-1-propene-3-d1 
• 76524-49-7 C₁₄H₁₆⁽²⁾HN 
• 130946-98-4 (2-formyl-1-phenylethenyl)diphenyl(3-sulfophenyl)phosphonium chloride, sodium salt 

Relevant articles and documents

Iron-Catalyzed ?±,?-Dehydrogenation of Carbonyl Compounds

An iron-catalyzed α,β-dehydrogenation of carbonyl compounds was developed. A broad spectrum of carbonyls or analogues, such as aldehyde, ketone, lactone, lactam, amine, and alcohol, could be converted to their α,β-unsaturated counterparts in a simple one-step reaction with high yields.

Silicon-directed rhenium-catalyzed allylic carbaminations and oxidative fragmentations of γ-silyl allylic alcohols

A highly regioselective allylic substitution of β-silyl allylic alcohols has been achieved that provides the branched isomer as a single product. This high level of regiocontrol is achieved through the use of a vinyl silane group that can perform a Hiyama coupling providing 1,3-disubstituted allylic amines. An unusual oxidative fragmentation product was also observed at elevated temperature that appears to proceed by a Fleming-Tamao-type oxidation-elimination pathway.

ORGANIC CHEMISTRY IN WATER (PART V) NUCLEOPHILIC ADDITION OF WATER-SOLUBLE PHOSPHINES ON ACTIVATED ALKYNES: AN EFFICIENT SYNTHESIS OF NEW VINYLPHOSPHONIUM SALTS AND OF SPECIFICALLY DEUTERATED OLEFINS.

Triphenylphosphine m-trisulfonate 1 and triphenylphosphine m-monosulfonate 2 react in water with activated alkynes R-CC-A (A = CO2H, CO2R1, COR2, CHO) affording new vinylphosphonium salts or vinylphosphine oxides or alkenes depending on the pH of the aqueous solution and on the nature of the substituent R.The reactions of 1 or 2 with alkynes bearing an electron-acceptor substituent R give rise to the corresponding trans disubstituted olefins.Specifically mono or dideuterated alkenes are thus obtained in good yields by sequential use of H2O-D2O.When R = H or Alkyl, vinylphosphonium salts or vinylphosphine oxides are quantitatively produced respectively in acidic or in neutral solution.