130995-13-0Relevant articles and documents
Insight into the Electronic State of 1-Phenylthienoborepin by Means of Nuclear Magnetic Resonance Spectroscopy
Sugihara, Yoshikazu,Miyatake, Ryuta,Yagi, Toshiyasu
, p. 933 - 936 (1993)
In order to obtain an insight into the electronic states in connection with the condensation modes of thiophene and borepin rings, we examined 1-phenylthienoborepin (2).While 1-phenylthienoborepin is a peripherally conjugated compound, 2 was shown to be an aromatic compound which maintains characteristics in conjugation of individual rings.
Synthesis and Photochemical Application of Hydrofluoroolefin (HFO) Based Fluoroalkyl Building Block
Varga, Bálint,Tóth, Balázs L.,Béke, Ferenc,Csenki, János T.,Kotschy, András,Novák, Zoltán
supporting information, p. 4925 - 4929 (2021/07/01)
A novel fluoroalkyl iodide was synthesized on multigram scale from refrigerant gas HFO-1234yf as cheap industrial starting material in a simple, solvent-free, and easily scalable process. We demonstrated its applicability in a metal-free photocatalytic ATRA reaction to synthesize valuable fluoroalkylated vinyl iodides and proved the straightforward transformability of the products in cross-coupling chemistry to obtain conjugated systems.
γ-Carboline synthesis enabled by Rh(iii)-catalysed regioselective C-H annulation
Jiang, Bo,Jia, Jingwen,Sun, Yufei,Wang, Yichun,Zeng, Jing,Bu, Xiubin,Shi, Liangliang,Sun, Xiaoying,Yang, Xiaobo
supporting information, p. 13389 - 13392 (2020/11/10)
A redox-neutral Rh(iii)-catalyzed C-H annulation of indolyl oximes was developed. Relying on the use of various alkynyl silanes as the terminal alkyne surrogates, the reaction exhibited a reverse regioselectivity, thus giving an exclusive and easy way for the synthesis of a wide range of substituent free γ-carbolines at C3 position with high efficiency. Deuterium-labelling experiments and kinetic analysis have preliminarily shed light on the working mode of this catalytic system. This journal is
Gold-Catalyzed Dimerization of Diarylalkynes: Direct Access to Azulenes
Claus, Vanessa,Schukin, Michael,Harrer, Siegfried,Rudolph, Matthias,Rominger, Frank,Asiri, Abdullah M.,Xie, Jin,Hashmi, A. Stephen K.
supporting information, p. 12966 - 12970 (2018/09/25)
We have developed a simple gold-catalyzed procedure for the synthesis of substituted and modifiable azulenes. The azulenes are formed either by the dimerization of push–pull diarylalkynes bearing a fluorine atom in ortho or para position or by the dimeriz
