131029-14-6Relevant articles and documents
Visible light induced redox neutral fragmentation of 1,2-diol derivatives
Chen, Kang,Schwarz, Johanna,Karl, Tobias A.,Chatterjee, Anamitra,K?nig, Burkhard
, p. 13144 - 13147 (2019/11/11)
A homogeneous, redox-neutral photo fragmentation of diol derivatives was developed. Under photo/hydrogen atom transfer (HAT) dual catalysis, diol derivatives such as lignin model compounds and diol monoesters undergo selective β C(sp3)-O bond cleavage to afford ketones, phenols and acids effectively.
CuI/l-proline-catalyzed selective one-step mono-acylation of styrenes and stilbenes
Prathima, P. Sai,Maheswari, C. Uma,Srinivas,Rao, M. Mohan
supporting information; experimental part, p. 5771 - 5774 (2010/11/05)
Vicinal di-oxygenation of styrene-type olefins was achieved with cheaper, less toxic CuI in the presence of l-proline as ligand and NaIO4 as the oxidant. This approach provides a straightforward and efficient access to mono-acylated diols from both styrene and stilbene derivatives with good to excellent yields and diastereoselectivity.
Chemoenzymatic synthesis of enantiomerically pure 1,2-diols employing immobilized lipase in the ionic liquid [bmim]PF6
Kamal, Ahmed,Chouhan, Gagan
, p. 8801 - 8805 (2007/10/03)
Significantly enhanced enantioselectivity in the enzymatic kinetic resolution of 1,2-diols employing immobilized lipase from Pseudomonas cepacia (PS-C, 'Amano') results from the use of the ionic liquid [bmim]PF6 as reaction medium.