1310742-32-5Relevant articles and documents
C-C or C-O bond cleavage in a phenolic lignin model compound: Selectivity depends on vanadium catalyst
Hanson, Susan K.,Wu, Ruilian,Silks, Louis A. Pete
supporting information; experimental part, p. 3410 - 3413 (2012/06/30)
The aerobic oxidation of a phenolic lignin model compound with a vanadium catalyst results in the oxidative cleavage of the C-C bond between the aryl ring and the adjacent hydroxy-substituted carbon atom (see scheme). Labeling experiments indicate key mechanistic differences to a previously reported related C-O bond cleavage reaction. The selectivity in C-C versus C-O bond cleavage depends on the choice of the vanadium catalyst. Copyright