131139-94-1

Basic information

• Product Name: (1'R,2'R,3S)-2'-hydroxycyclohexyl 3-methylheptanoate
• CAS NO: 131139-94-1
• Molecular Weight: 242.359
• Mol File: 131139-94-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1'R,2'R,3S)-2'-hydroxycyclohexyl 3-methylheptanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (1'R,2'R,3S)-2'-hydroxycyclohexyl 3-methylheptanoate(131139-94-1)
• EPA Substance Registry System: (1'R,2'R,3S)-2'-hydroxycyclohexyl 3-methylheptanoate(131139-94-1)

Safety Data

• Hazardous Substances Data: 131139-94-1(Hazardous Substances Data)

Upstream product

• 24406-16-4 lithium di-n-butylcuprate 
• 131140-02-8 (1R,2R)-2-hydroxycyclohexyl crotonate 
• 1072-86-2 (1R,2R)-trans-1,2-cyclohexanediol 
• 13858-62-3 (1R,2R)-1-acetoxy-2-cyclohexanol 
• 1759-71-3 trans-1,2-cyclohexanediol diacetate 

Downstream Products

• 61169-84-4 (S)-3-methylheptan-1-ol 

Relevant articles and documents

Asymmetric conjugate addition of organometallic reagents to chiral α,β-unsaturated esters

Asymmetric conjugate addition to α,β-unsaturated ester was studied using four kinds of cyclic diols (1c-4c) as chiral auxiliaries. Among the tested substrates, (R,R)-cyclohexane-1,2-diol derivatives (6a-c) and (1R,2S)-2-hydroxymethylcyclopentanol derivative (7a) showed high and reverse diastereoselectivity in conjugate addition by organocuprates (R2CuLi) and/or Grignard reagents in the presence of copper iodide (RMgBr + CuI), respectively.