131178-73-9

Basic information

• Product Name: 1-p-anisyl-2-naphthyl methyl sulfide
• CAS NO: 131178-73-9
• Molecular Weight: 280.39
• Mol File: 131178-73-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-p-anisyl-2-naphthyl methyl sulfide(CAS DataBase Reference)
• NIST Chemistry Reference: 1-p-anisyl-2-naphthyl methyl sulfide(131178-73-9)
• EPA Substance Registry System: 1-p-anisyl-2-naphthyl methyl sulfide(131178-73-9)

Safety Data

• Hazardous Substances Data: 131178-73-9(Hazardous Substances Data)

Upstream product

• 696-62-8 para-iodoanisole 
• 89781-11-3 potassium 2-naphthalenethiolate 
• 74-88-4 methyl iodide 

Relevant articles and documents

Regiochemistry of the Coupling of Aryl Radicals with Nucleophiles Derived from the Naphthyl System. Experimental and Theoretical Studies

We here report the photostimulated reaction of unactived aromatic halides with ambident nucleophiles derived from the naphthyl system such as 1- and 2-naphthylamide, 2-naphthoxide, 2-naphthalenethiolate, and 2 naphthaleneselenate ions, by the SRN1 mechanism of nucleophilic substitution.According to our experimental results, C-arylation in position 1 of the naphthyl moiety is the only reaction observed with 2-naphthoxide ions and it is favored over N-arylation with 1- and 2-naphthylamide ions.Heteroatom arylation is preferred over C-arylation with 2-naphthalenethiolate ions while it is the only observed reaction with 2-naphthaleneselenate ions.A theoretical study was carried out to explain the regiochemistry of the system.In competition experiments, 2-naphthalenethiolate ions proved to be 1.8 +/- 0.2 times more reactive than 2-naphthoxide ions for C-substitution toward p-anisyl radicals in liquid ammonia.