1312208-27-7Relevant articles and documents
Effect of high pressure on the organocatalytic asymmetric michael reaction: Highly enantioselective synthesis of γ-nitroketones with quaternary stereogenic centers
Kwiatkowski, Piotr,Dudzinski, Krzysztof,Lyzzwa, Dawid
supporting information; experimental part, p. 3624 - 3627 (2011/09/15)
The significant effect of hydrostatic pressure on the difficult organocatalytic 1,4-conjugate addition of nitroalkanes to prochiral sterically congested β,β-disubstituted enones is demonstrated. This approach allows for the synthesis of γ-nitroketones con