1312597-61-7Relevant articles and documents
Enabling bifunctionality and hemilability of N-heteroaryl NHC complexes
Specht, Zephen G.,Cortes-Llamas, Sara A.,Tran, Hai N.,Van Niekerk, Christoffel J.,Rancudo, Khing T.,Golen, James A.,Moore, Curtis E.,Rheingold, Arnold L.,Dwyer, Tammy J.,Grotjahn, Douglas B.
, p. 6606 - 6609 (2011)
Functionalized carbene ligands: Increasing the steric bulk of R1 on 1 from H to tBu results in lengthening of the M-N bond (by up to 9 %), lowered activation energy for chelate opening (cf. 2) by 17 kcal mol -1, and improved binding