131356-53-1

Basic information

• Product Name: Benzene, 1-(2,2-dibromoethenyl)-4-(trifluoromethyl)-
• CAS NO: 131356-53-1
• Molecular Formula: C9H5Br2F3
• Molecular Weight: 329.942
• Mol File: 131356-53-1.mol
• Article Data: 32

Chemical Properties

• CAS DataBase Reference: Benzene, 1-(2,2-dibromoethenyl)-4-(trifluoromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-(2,2-dibromoethenyl)-4-(trifluoromethyl)-(131356-53-1)
• EPA Substance Registry System: Benzene, 1-(2,2-dibromoethenyl)-4-(trifluoromethyl)-(131356-53-1)

Safety Data

• Hazardous Substances Data: 131356-53-1(Hazardous Substances Data)

Upstream product

• 455-19-6 4-Trifluoromethylbenzaldehyde 
• 558-13-4 carbon tetrabromide 
• 189096-91-1 {[4-(trifluoromethyl)phenyl]methylidene}hydrazine 

Downstream Products

• 3038-60-6 2-(4-trifluoromethylphenyl)methylimidazoline 
• 1353724-86-3 ethyl 1-bromo-2-(4-(trifluoromethyl)phenyl)indolizine-3-carboxylate 
• 313343-88-3 1-(bromoethynyl)-4-(trifluoromethyl)benzene 
• 1426841-25-9 2,2-dimethyl-4-(4-(trifluoromethyl)phenyl)but-3-ynenitrile 
• 1429762-73-1 (E)-diphenyl(4-(trifluoromethyl)styryl)phosphine oxide 
• 1429762-74-2 diphenyl(4-(trifluoromethyl)styryl)phosphine oxide 
• 1027335-55-2 (E)-2-(4-(trifluoromethyl)styryl)pyridine 
• 173546-21-9 3-(4-trifluoromethylphenyl)prop-2-yn-1-ol 
• 294634-81-4 1-((Z)-2-Bromo-but-1-en-3-ynyl)-4-trifluoromethyl-benzene 
• 491859-73-5 1-(4-trifluoromethylphenyl)pent-1-yn-3-ol 
• 87212-82-6 (Z)-1-(2-bromovinyl)-4-(trifluoromethyl)benzene 
• 512787-33-6 1-(pyrrolidin-1-yl)-2-(4-(trifluoromethyl)phenyl)ethan-1-one 

Relevant articles and documents

Anionic sigmatropic-electrocyclic-chugaev cascades: Accessing 12-aryl-5-(methylthiocarbonylthio)tetracenes and a related anthra[2,3-b]thiophene

1,4-Diols resulting from the double addition of ArCCLi (Ar = Ph, substituted phenyl, 2-thienyl) to ortho-C6H4(CHO)2 undergo cascades to tetracenes on simple admixture of LiHDMS, CS2 and MeI. Acene formation proceeds by [3,3]-sigmatropic rearrangement of xanthate anions followed by 6π electrocyclisations. The reactions are terminated by E2 or anionic Chugaev-type eliminations. Structural packing motifs and electronic properties are reported for the tetracenes.

Selective Rhodium-Catalyzed Hydroformylation of Terminal Arylalkynes and Conjugated Enynes to (Poly)enals Enabled by a π-Acceptor Biphosphoramidite Ligand

The hydroformylation of terminal arylalkynes and enynes offers a straightforward synthetic route to the valuable (poly)enals. However, the hydroformylation of terminal alkynes has remained a long-standing challenge. Herein, an efficient and selective Rh-catalyzed hydroformylation of terminal arylalkynes and conjugated enynes has been achieved by using a new stable biphosphoramidite ligand with strong π-acceptor capacity, which affords various important E-(poly)enals in good yields with excellent chemo- and regioselectivity at low temperatures and low syngas pressures.

N -tert-butyl -2 -phenylindole derivative Preparation method and application

The invention belongs to the technical field of organic synthesis, and particularly relates to N - tert-butyl -2 -phenyl indole derivatives as well as a preparation method and application thereof. The preparation method comprises the following steps: (Z)-1 - bromo -1 - phenyl -2 - styrene derivative, N, N - di-tert-butyl diazepinone, palladium catalyst, monophosphine ligand, hydrocarbon activator, base and first solvent, and N -tert-butyl -2 -aryl indole derivatives which can synthesize substituent type diversity, and the prepared N -tert-butyl -2 -aryl indole derivative can be used for preparing biologically active molecules N -2 .