131457-61-9

Basic information

• Product Name: diadamantylsilane
• CAS NO: 131457-61-9
• Molecular Weight: 300.56
• Mol File: 131457-61-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: diadamantylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: diadamantylsilane(131457-61-9)
• EPA Substance Registry System: diadamantylsilane(131457-61-9)

Safety Data

• Hazardous Substances Data: 131457-61-9(Hazardous Substances Data)

Upstream product

• 758-21-4 dimethylethylsilane 
• 131457-59-5 2,2-diadamantyl-1,1,3,3-tetramethyl-1,3-diphenyltrisilane 
• 513-81-5 2,3-dimethyl-buta-1,3-diene 

Relevant articles and documents

Diadamantylsilylene and its stereochemistry of addition

Lithium-induced dehalogenation assisted by ultrasonic irradiation of diadamantyldiiodosilane in the presence of olefins and alkynes leads to high yields of 1,1 -diadamantylsiliranes and 1,1 -diadamantylsilirenes, respectively. The siliranes are precursors for the efficient thermal and photochemical generation of diadamantylsilylene (Ad2Si:). The addition of thermally generated Ad2Si: to cis- and trans-2-butene and -3-hexene is totally stereospecific, implying reaction from a singlet electronic state of the silylene. Photoisomerization of cis- and trans-1,1 -diadamantylsiliranes complicates the study of the stereochemistry of addition of photogenic Ad2Si:, but again a high degree of stereospecificity is observed.