13148-28-2

Basic information

• Product Name: Aziridine, 1,2-dimethyl-3-phenyl-, (2S,3S)-
• CAS NO: 13148-28-2
• Molecular Formula: C10H13N
• Molecular Weight: 147.22
• Mol File: 13148-28-2.mol
• Article Data: 13

Chemical Properties

• CAS DataBase Reference: Aziridine, 1,2-dimethyl-3-phenyl-, (2S,3S)-(CAS DataBase Reference)
• NIST Chemistry Reference: Aziridine, 1,2-dimethyl-3-phenyl-, (2S,3S)-(13148-28-2)
• EPA Substance Registry System: Aziridine, 1,2-dimethyl-3-phenyl-, (2S,3S)-(13148-28-2)

Safety Data

• Hazardous Substances Data: 13148-28-2(Hazardous Substances Data)

Upstream product

• 873-66-5 1-propenylbenzene 
• 87214-07-1 (4S,5R)-3,4-Dimethyl-2,5-diphenyl-[1,3,2]oxazaphospholidine 
• 116432-33-8 (+)-(2R,3S)-3,4-dimethyl-2,5-diphenyl-nitrobenzo<4,3-g>1,6-dioxa-4-aza-5-phospha (5-PV) spiro <4.4>nonane 
• 50-98-6 ephedrine hydrochloride 
• 65960-90-9 (2R)-3,4c-dimethyl-5c-phenyl-2-thioxo-2λ⁵-[1,3,2]oxazaphospholidin-2r-ylamine 
• 90-82-4 pseudoephedrine 
• 97101-92-3 (S)-Difluoromethyl-phosphonothioic acid O-ethyl ester O-((1R,2S)-2-methylamino-1-phenyl-propyl) ester; hydrochloride 
• 97101-91-2 (S)-Fluoromethyl-phosphonothioic acid O-ethyl ester O-((1R,2S)-2-methylamino-1-phenyl-propyl) ester; hydrochloride 
• 79756-20-0 ((1S,2R)-2-Bromo-1-methyl-2-phenyl-ethyl)-methyl-amine; hydrochloride 
• 90-81-3 (-)-erythro-Ephedrine 
• 141-52-6 sodium ethanolate 
• 299-42-3 ephedrine 

Downstream Products

• 908343-65-7 (4S,5R)-cis-3-methylamino-4-methyl-5-phenylthiazolidine-2-thione 
• 154550-36-4 (αR,βS)-α,N-dimethyl-β-(phenylthio)benzeneethanamine 
• 154550-38-6 (2S,5R)-3-(N-methyl)-4-methyl-5-phenyl-2,2-dimethyl-1,3-thiazolane 
• 2226-27-9 (1R,2S)-1-phenyl-2-(N-methyl-N-acetamido)propanethiol 
• 537-46-2 Methamphetamin 
• 16251-47-1 (4S,5S)-3,4-dimethyl-5-phenyl-1,3-oxazolidin-2-one 
• 73393-59-6 (-)-(1R,2S)-(2-methylamino-1-phenylpropyl)diphenylphosphane 
• 69351-58-2 bis-((1R,2S)-2-methylamino-1-phenyl-propyl)-disulfide 
• 2784-28-3 (1R,2S)-1-phenyl-2-(N-methylamino)propanethiol hydrochloride 

Relevant articles and documents

Stereospecific Alkene Aziridination Using a Bifunctional Amino-Reagent: An Aza-Prilezhaev Reaction

In situ deprotection (TFA) of O-Ts activated N-Boc hydroxylamines triggers intramolecular aziridination of N-tethered alkenes to provide complex N-heterocyclic ring systems. Synthetic and computational studies corroborate a diastereospecific aza-Prilezhaev-type mechanism. The feasibility of related intermolecular alkene aziridinations is also demonstrated.

Experimental and theoretical investigations for the regio and stereoselective transformation of trans 1,2,3-trisubstituted aziridines into trans oxazolidin-2-ones

The regio and stereoselective transformation of trans 1,2,3-trisubstituted aziridines into trans oxazolidin-2-ones takes place in good yield. However, the cis configuration at C2 and C3 in monocyclic aziridines is a limiting factor for this transformation

Aminosulf(ox)ides as Ligands for Iridium(I)-Catalyzed Asymmetric Transfer Hydrogenation

A new class of efficient catalysts was developed for the asymmetric transfer hydrogenation of unsymmetrical ketones. A series of chiral N,S-chelates (6-22) was synthesized to serve as ligands in the iridium(I)-catalyzed reduction of ketones. Both formic a