1315277-22-5

Basic information

• Product Name: 9-bromo-10-m-tolylbicyclo[6.2.0]dec-9-ene
• Synonyms: 9-bromo-10-m-tolylbicyclo[6.2.0]dec-9-ene
• CAS NO: 1315277-22-5
• Molecular Weight: 305.258
• Mol File: 1315277-22-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9-bromo-10-m-tolylbicyclo[6.2.0]dec-9-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-bromo-10-m-tolylbicyclo[6.2.0]dec-9-ene(1315277-22-5)
• EPA Substance Registry System: 9-bromo-10-m-tolylbicyclo[6.2.0]dec-9-ene(1315277-22-5)

Safety Data

• Hazardous Substances Data: 1315277-22-5(Hazardous Substances Data)

Upstream product

• 33675-43-3 1-(bromo-ethynyl)-3-methyl-benzene 
• 931-88-4 1,2-cyclooctene 
• 766-82-5 1-ethynyl-3-methyl-benzene 

Relevant articles and documents

Palladium-catalyzed bromoalkynylation of C-C double bonds: Ring-structure-dependent synthesis of 7-alkynyl norbornanes and cyclobutenyl halides

Strain versus flexibility: The palladium-catalyzed reaction of haloalkynes with norbornene derivatives leads to 7-alkynyl norbornane products (see scheme). Key to the success of this reaction is the formation of a "bridging" palladium species, which can rearrange to result in a C-7 functionalization. The ring-structure-dependent [2+2] cycloaddition of haloalkynes with cyclooctene has been achieved in moderate to good yields under similar conditions. Copyright