131543-60-7

Basic information

• Product Name: (3aR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-(iodomethyl)-2H-cyclopentafuran-2-one

Upstream product

• 39746-00-4 (1S,5R,6S,7R)-7-benzoyloxy-6-hydroxymethyl-2-oxabicyclo[3.3.0]octan-3-one 
• 131543-59-4 (3aR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-(bromomethyl)-2H-cyclopentafuran-2-one 

Downstream Products

• 172821-93-1 (3aR,4R,5R,6aS)-4-(hydroxymethyl)-2-oxohexahydro-2H-cyclopenta[b]furan-5-yl benzoate 
• 131543-64-1 (3aR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-((2R,3R)-2,3-epoxy-4-hydroxybutyl)-2H-cyclopentafuran-2-one 
• 131543-64-1 Benzoic acid (3aR,4R,5R,6aS)-4-(3-hydroxymethyl-oxiranylmethyl)-2-oxo-hexahydro-cyclopenta[b]furan-5-yl ester 
• 131543-67-4 (3aR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-((2R)-2-(phenylsulfinyl)-(3S)-3-hydroxy-4-phenoxybutyl)-2H-cyclopentafuran-2-one 
• 131543-61-8 (3aR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-((2S)-2-hydroxy-(3S)-3-(phenylthio)-4-phenoxybutyl)-2H-cyclopentafuran-2-one 
• 131543-66-3 (3aR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-((2R)-2-(phenylthio)-(3S)-3-hydroxy-4-phenoxybutyl)-2H-cyclopentafuran-2-one 
• 51638-92-7 (3aR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-((3R)-3-hydroxy-4-phenoxy-1(E)-butenyl)-2H-cyclopentafuran-2-one 
• 131543-65-2 (3aR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-((2R,3R)-2,3-epoxy-4-phenoxybutyl)-2H-cyclopentafuran-2-one 
• 131543-63-0 (3aR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-(4-hydroxy-2(E)-butenyl)-2H-cyclopentafuran-2-one 
• 131543-62-9 (3aR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-(4-(tert-butyldimethylsiloxy)-2(E)-butenyl)-2H-cyclopentafuran-2-one 

Relevant articles and documents

Stereoselective preparation of key intermediates for the synthesis of iso-, neuro- and phyto-prostane family members: Inaugural asymmetric synthesis of 17-E2c-dihomo- and 17-F2c-dihomo-isoprostanes

A practical methodology for the synthesis of key intermediates for isoprostane, neuroprostane and dihomo-isoprostane preparation has been described. The key strategy involved a three stage C-12 stereocenter inversion of the configuration of a Corey lacton