131567-49-2Relevant articles and documents
Regioselective Diboron-Mediated Semireduction of Terminal Allenes
Gates, Ashley M.,Santos, Webster L.
, p. 4619 - 4624 (2019/12/11)
A method for the regioselective reduction of the terminal double bond of 1,1-disubstituted allenes has been developed. In the presence of a palladium catalyst, tetrahydroxydiboron and stoichiometric water, allene semireduction proceeds in high yield to afford Z-alkenes selectively.
Nickel-catalyzed substitution reactions of propargyl halides with organotitanium reagents
Li, Qing-Han,Liao, Jung-Wei,Huang, Yi-Ling,Chiang, Ruei-Tang,Gau, Han-Mou
, p. 7634 - 7642 (2014/12/11)
A simple and mild catalytic coupling reaction of propargyl halides with organotitanium reagents is reported. The reaction of propargyl bromide with organo-titanium reagents mediated by NiCl2(2 mol%) and PCy3(4 mol%) in CH2