131612-02-7

Basic information

• Product Name: Co(ClC₆H₄NC)2(P(OC₂H₅)2C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Co(ClC₆H₄NC)2(P(OC₂H₅)2C₆H₅)3PF₆
• CAS NO: 131612-02-7
• Molecular Weight: 1073.7
• Mol File: 131612-02-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Co(ClC₆H₄NC)2(P(OC₂H₅)2C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Co(ClC₆H₄NC)2(P(OC₂H₅)2C₆H₅)3PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: Co(ClC₆H₄NC)2(P(OC₂H₅)2C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Co(ClC₆H₄NC)2(P(OC₂H₅)2C₆H₅)3PF₆(131612-02-7)
• EPA Substance Registry System: Co(ClC₆H₄NC)2(P(OC₂H₅)2C₆H₅)3⁽¹⁺⁾*PF₆^(1-)=Co(ClC₆H₄NC)2(P(OC₂H₅)2C₆H₅)3PF₆(131612-02-7)

Safety Data

• Hazardous Substances Data: 131612-02-7(Hazardous Substances Data)

Upstream product

• 1885-81-0 p-chlorophenyl isocyanide 
• 131611-98-8 CoH(P(OC₂H₅)2(C₆H₅))4⁽¹⁺⁾*ClO₄^(1-)=CoH(P(OC₂H₅)2(C₆H₅))4ClO₄ 

Relevant articles and documents

Reactivity of the Hydride 4> with RN2+ (R = aryl), NO+, and H+ Cations: Preparation and Properties of New Cobalt Complexes. Measurements of T1 for 4> and 4>BPh4

The reaction of 4> with RN2+ (R = 4-CH3C6H4) affords the paramagnetic cationic hydride 4>+, with NO+ the dinitrosyl cation 2>+, and with HBF4*Et2O the cationic dihydride 4>+.Characterization of the complexes by i.r., e.s.r., and variable-temperatrure 1H and 31P- n.m.r. spectra is described.Variable-temperature 1H n.m.r.T1 measurements at 80, 200, and 400 MHz for both 4> and 4>BPh4 are also reported.The reactivity of the cationic hydrides with CO, RNC, NO,I2, and RN2+ was investigated and the new cations 3>+ (R = 4-CH3C6H4, 4-CH3OC6H4, or 4-ClC6H4) and 4>+ synthesized.The unstable intermediate 4>+ -1> was also detected.