1316239-75-4Relevant articles and documents
A regio- and stereoselective synthesis of trisubstituted alkenes via gold(i)-catalyzed hydrophosphoryloxylation of haloalkynes
Chary, Bathoju Chandra,Kim, Sunggak,Shin, Doosup,Lee, Phil Ho
supporting information; experimental part, p. 7851 - 7853 (2011/09/12)
A new stereoselective synthesis of trisubstituted alkenes is developed. Hydrophosphoryloxylation of haloalkynes provides Z-alkenyl halophosphates, which undergo Pd-catalyzed consecutive cross-coupling reactions to afford regio- and stereodefined trisubsti