131846-19-0

Basic information

• Product Name: methyl 1-homo-3,4-cis-didehydro-9,15-diketo-16-phenoxy-17,18,19,20-tetranorprostenoate
• CAS NO: 131846-19-0
• Molecular Weight: 398.499
• Mol File: 131846-19-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 1-homo-3,4-cis-didehydro-9,15-diketo-16-phenoxy-17,18,19,20-tetranorprostenoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 1-homo-3,4-cis-didehydro-9,15-diketo-16-phenoxy-17,18,19,20-tetranorprostenoate(131846-19-0)
• EPA Substance Registry System: methyl 1-homo-3,4-cis-didehydro-9,15-diketo-16-phenoxy-17,18,19,20-tetranorprostenoate(131846-19-0)

Safety Data

• Hazardous Substances Data: 131846-19-0(Hazardous Substances Data)

Upstream product

• 40665-68-7 dimethyl (3-phenoxy-2-oxopropyl)phosphonate 
• 88736-15-6 2α-(7-methoxycarbonyl-4Z-heptenyl)-3β-formylcyclopentanone 

Downstream Products

• 131846-21-4 (Z)-8-[(1S,2S)-2-((E)-(S)-3-Hydroxy-4-phenoxy-but-1-enyl)-5-oxo-cyclopentyl]-oct-4-enoic acid methyl ester 
• 131846-21-4 (Z)-8-[(1S,2S)-2-((E)-(R)-3-Hydroxy-4-phenoxy-but-1-enyl)-5-oxo-cyclopentyl]-oct-4-enoic acid methyl ester 
• 131846-23-6 (Z)-8-[(1S,2R,5S)-2-Hydroxy-5-((E)-(S)-3-hydroxy-4-phenoxy-but-1-enyl)-cyclopentyl]-oct-4-enoic acid methyl ester 
• 131846-23-6 (Z)-8-[(1S,2R,5S)-2-Hydroxy-5-((E)-(R)-3-hydroxy-4-phenoxy-but-1-enyl)-cyclopentyl]-oct-4-enoic acid methyl ester 
• 131846-23-6 (Z)-8-[(1S,2S,5S)-2-Hydroxy-5-((E)-(R)-3-hydroxy-4-phenoxy-but-1-enyl)-cyclopentyl]-oct-4-enoic acid methyl ester 
• 131846-22-5 (Z)-8-{(1S,2S,5S)-2-[(E)-(S)-4-(3-Chloro-phenoxy)-3-hydroxy-but-1-enyl]-5-hydroxy-cyclopentyl}-oct-4-enoic acid methyl ester 

Relevant articles and documents

PROSTANOIDS XXXIII. INVESTIGATION OF THE POSSIBILITIES FOR CHEMOSELECTIVE AND STEREOSELECTIVE REDUCTION OF THE METHYL ESTERS OF (+/-)-1-HOMO-3,4-CIS-DIDEHYDRO-16-PHENOXY(m-CHLOROPHENOXY)-17,18,19,20-TETRANOR-9,15-DIKETO-13,14-TRANS-PROSTENOIC ACIDS

Chemoselective and stereoselective reduction of the methyl esters of 1-homo-3,4-cis-didehydro-16-phenoxy(m-chlorophenoxy)-17,18,19,20-tetranor-9,15-diketo-13,14-trans-prostenoic acid by triisobutylaluminum and L-selectride (methylene chloride, -70 deg C) gave the corresponding esters of 11-deoxyprostaglandins of the E and F types.