131927-91-8

Basic information

• Product Name: (3S)-1-<(2R,5S)-<(1R)-1-Benzyloxymethoxyethyl>-5-ethyltetrahydrofur-2-yl>-3-<(4S,5S)-5-ethyl-2,2-dimethyl-1,3-dioxan-4-yl>butan-1-one
• Synonyms: (3S)-1-<(2R,5S)-<(1R)-1-Benzyloxymethoxyethyl>-5-ethyltetrahydrofur-2-yl>-3-<(4S,5S)-5-ethyl-2,2-dimethyl-1,3-dioxan-4-yl>butan-1-one
• CAS NO: 131927-91-8
• Molecular Weight: 476.654
• Mol File: 131927-91-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3S)-1-<(2R,5S)-<(1R)-1-Benzyloxymethoxyethyl>-5-ethyltetrahydrofur-2-yl>-3-<(4S,5S)-5-ethyl-2,2-dimethyl-1,3-dioxan-4-yl>butan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: (3S)-1-<(2R,5S)-<(1R)-1-Benzyloxymethoxyethyl>-5-ethyltetrahydrofur-2-yl>-3-<(4S,5S)-5-ethyl-2,2-dimethyl-1,3-dioxan-4-yl>butan-1-one(131927-91-8)
• EPA Substance Registry System: (3S)-1-<(2R,5S)-<(1R)-1-Benzyloxymethoxyethyl>-5-ethyltetrahydrofur-2-yl>-3-<(4S,5S)-5-ethyl-2,2-dimethyl-1,3-dioxan-4-yl>butan-1-one(131927-91-8)

Safety Data

• Hazardous Substances Data: 131927-91-8(Hazardous Substances Data)

Upstream product

• 128531-41-9 (2S,5R)-2-<(1R)-1-Benzyloxymethoxyethyl>-2-ethyl-5-formyltetrahydrofuran 
• 131967-58-3 (2S)-2-<(4S,5S)-5-Ethyl-2,2-dimethyl-1,3-dioxan-4-yl>propyl phenyl sulfone 
• 110653-58-2 (2R,3R,4S)-4-benzyloxymethyl-3-formyloxy-2-methylhexanal 
• 144534-92-9 (4R,5S)-5-Ethyl-4-((R)-2-iodo-1-methyl-ethyl)-2,2-dimethyl-[1,3]dioxane 
• 152934-39-9 (2S)-2-<(4S,5S)-5-Ethyl-2,2-dimethyl-1,2-dioxan-4-yl>propan-1-ol 
• 152934-37-7 (2S,3S,4S)-2-Ethyl-4-methyl-5-pivaloyloxypentane-1,3-diol 
• 152934-35-5 (2S,3S,4S)-4-Benzyloxymethyl-2-methylhexane-1,3-diol 
• 152934-38-8 (4S,5S,1'S)-2,2-dimethyl-5-ethyl-4-<1'-methyl-2'-(trimethylacetoxy)ethyl>-1,3-dioxane 
• 153977-33-4 (2S)-2-<(4S,5S)-5-Ethyl-2,2-dimethyl-1,2-dioxan-4-yl>-1-tosyloxypropane 
• 152934-36-6 (2S,3S,4S)-4-Benzyloxymethyl-3-hydroxy-2-methyl-1-pivaloyloxyhexane 

Downstream Products

• 131967-62-9 (2S)-2-<(2S,3S,5R)-5-<(2R,5S)-5-((1R)-1-Benzyloxymethoxyethyl)-5-ethyltetrahydrofur-2-yl>-5-ethenyl-3-methyltetrahydrofur-2-yl>butan-1-ol 
• 131927-96-3 (4S)-4-<(2S,3S,5R)-5-<(2R,5S)-5-((1R)-1-Benzyloxymethoxyethyl)-5-ethyltetrahydrofur-2-yl>-5-ethyl-3-methyltetrahydrofur-2-yl>hexan-3-one 
• 152934-49-1 (2R)-2-<(2S,3S,5R)-5-<(2R,5S)-5-((1R)-1-Benzyloxymethoxyethyl)-5-ethyltetrahydrofur-2-yl>-5-ethenyl-3-methyltetrahydrofur-2-yl>butanal 
• 152934-48-0 {(S)-2-[(2R,4S,5S,2'R,5'S)-5'-((R)-1-Benzyloxymethoxy-ethyl)-5'-ethyl-4-methyl-2-vinyl-octahydro-[2,2']bifuranyl-5-yl]-butoxy}-tert-butyl-dimethyl-silane 
• 54156-67-1 Isolasalocid A 
• 152934-45-7 (2S)-2-<(2S,3S,5R)-5-<(2R,5S)-5-((1R)-Benzyloxymethoxyethyl)-5-ethyltetrahydrofur-2-yl>-5-<(1E)-2-(4-methoxyphenyl)ethenyl>-3-methyltetrahydrofur-2-yl>butyl tert-butyldimethylsilyl ether 
• 152934-55-9 Benzyl 23-O-benzyloxymethylisolasalocid A 
• 131927-95-2 (2S)-2-<(2S,3S,5R)-5-<(2R,5S)-5-((1R)-Benzyloxymethoxyethyl)-5-ethyltetrahydrofur-2-yl>-5-<(1E)-2-(4-methoxyphenyl)ethenyl>-3-methyltetrahydrofur-2-yl>butan-1-ol 
• 131927-95-2 (2S)-2-<(2S,3S,5S)-5-<(2R,5S)-5-((1R)-Benzyloxymethoxyethyl)-5-ethyltetrahydrofur-2-yl>-5-<(1E)-2-(4-methoxyphenyl)ethenyl>-3-methyltetrahydrofur-2-yl>butan-1-ol 
• 25999-31-9 lasalocid (X 537 A) 
• 131967-60-7 (E)-(S)-3-[(2R,5S)-5-((R)-1-Benzyloxymethoxy-ethyl)-5-ethyl-tetrahydro-furan-2-yl]-5-((4S,5S)-5-ethyl-2,2-dimethyl-[1,3]dioxan-4-yl)-1-(4-methoxy-phenyl)-hex-1-en-3-ol 

Relevant articles and documents

Stereoselective Total Synthesis of Polyether Ionophore Antibiotics, Isolasalocid A and Lasalocid A. Part 2. The Total Synthesis via Stereoselective Construction of the B Rings by Chelation-Controlled Cyclization under Thermodynamic Conditions

Stereoselective total synthesis of isolasalocid A (1) and lasalocid A (2) was achieved via construction of the tetrahydrofuran rings by chelation-controlled cyclization of the corresponding p-methoxyphenyl substituted allyl alcohols (6, 7) under thermodyn