132114-06-8

Basic information

• Product Name: trans-5-(2-iodoanilino)-6-hydroxy-5,6-dihydro-1,10-phenanthroline
• Synonyms: trans-5-(2-iodoanilino)-6-hydroxy-5,6-dihydro-1,10-phenanthroline
• CAS NO: 132114-06-8
• Molecular Weight: 415.233
• Mol File: 132114-06-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: trans-5-(2-iodoanilino)-6-hydroxy-5,6-dihydro-1,10-phenanthroline(CAS DataBase Reference)
• NIST Chemistry Reference: trans-5-(2-iodoanilino)-6-hydroxy-5,6-dihydro-1,10-phenanthroline(132114-06-8)
• EPA Substance Registry System: trans-5-(2-iodoanilino)-6-hydroxy-5,6-dihydro-1,10-phenanthroline(132114-06-8)

Safety Data

• Hazardous Substances Data: 132114-06-8(Hazardous Substances Data)

Upstream product

• 615-43-0 2-iodophenylamine 
• 65115-91-5 5,6-epoxy-5,6-dihydro-[1,10]phenanthroline 
• 5144-89-8 1,10-phenanthroline hydrate 

Downstream Products

• 114622-04-7 ascididemin 
• 132142-67-7 N-(2-iodophenyl)-1,10-phenanthroline-5,6-quinone monoimine 

Relevant articles and documents

The synthesis of ascididemin

A short synthsis of the pentacyclic marine alkaloid ascididemin 1 (four steps, 21% yield) from 1,10-phenanthroline 16 is described. The key step, photocyclisation of the quinoneimine 14 in sulphuric acid, is the first such aza stilbene photocyclisation of a quinoneimine. Intermediate 14 is prepared in a single, but low yielding, step from the quinone 4 in an aza Wadsworth-Emmons reaction, or in much better yield from the epoxide 17 by treatment with 2- iodoaniline and triethylaluminium, followed by oxidation with barium manganate.