132114-79-5

Basic information

• Product Name: trimethyl(2-methoxy-4-methylphenoxy)silane
• Synonyms: trimethyl(2-methoxy-4-methylphenoxy)silane
• CAS NO: 132114-79-5
• Molecular Weight: 210.348
• Mol File: 132114-79-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: trimethyl(2-methoxy-4-methylphenoxy)silane(CAS DataBase Reference)
• NIST Chemistry Reference: trimethyl(2-methoxy-4-methylphenoxy)silane(132114-79-5)
• EPA Substance Registry System: trimethyl(2-methoxy-4-methylphenoxy)silane(132114-79-5)

Safety Data

• Hazardous Substances Data: 132114-79-5(Hazardous Substances Data)

Upstream product

• 93-51-6 2-Methoxy-4-methylphenol 
• 10416-58-7 N,N-bis(trimethylsilyl)acetamide 
• 999-97-3 1,1,1,3,3,3-hexamethyl-disilazane 

Relevant articles and documents

Nanocrystalline TiO2 as an efficient and reusable catalyst for the chemoselective trimethylsilylation of primary and secondary alcohols and phenols

Nanocrystalline TiO2 was used as an efficient and recyclable catalyst for the chemoselective trimethylsilylation of primary and less hindered secondary alcohols and phenols with hexamethyldisilazane (HMDS). All reactions were performed under mild and completely heterogeneous conditions in good to excellent yields.

Rice husk ash: A new, cheap, efficient, and reusable reagent for the protection of alcohols, phenols, amines, and thiols

Amild, efficient, and eco-friendly protocol for the protection of alcohols and phenols as trimethylsilyl ethers has been developed using rice husk ash as a reagent. This reagent is also able to catalyze the acetylation of alcohols, phenols, thiols, and amines with acetic anhydride. All reactions were performed under mild conditions in good to high yields. Copyright

Chemoselective and catalytic trimethylsilylation of alcohols and phenols by 1,1,1,3,3,3-hexamethyldisilazane and catalytic amounts of PhMe 3N+Br3-

An efficient procedure for the trimethylsilylation of alcohols and phenols is presented. The combination of 1,1,1,3,3,3-hexamethyldisilazane and a catalytic amount of phenyltrimethylammonium tribromide (PhMe3N +Br3-) was found to be effective for the trimethylsilylation of alcohols and phenols. The protection reaction is very simple and homogenously performed in dichloromethane at room temperature and mild conditions.