132140-40-0

Basic information

• Product Name: (CH₃)3PBH₂P(C₆H₅)2BH₂P(C₆H₅)2BH₂SO₃CH₃
• CAS NO: 132140-40-0
• Molecular Weight: 580.028
• Mol File: 132140-40-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (CH₃)3PBH₂P(C₆H₅)2BH₂P(C₆H₅)2BH₂SO₃CH₃(CAS DataBase Reference)
• NIST Chemistry Reference: (CH₃)3PBH₂P(C₆H₅)2BH₂P(C₆H₅)2BH₂SO₃CH₃(132140-40-0)
• EPA Substance Registry System: (CH₃)3PBH₂P(C₆H₅)2BH₂P(C₆H₅)2BH₂SO₃CH₃(132140-40-0)

Safety Data

• Hazardous Substances Data: 132140-40-0(Hazardous Substances Data)

Upstream product

• 75-75-2 methanesulfonic acid 
• 122953-49-5 (CH₃)3PBH₂P(C₆H₅)2BH₂P(C₆H₅)2BH₃ 

Downstream Products

• 122953-50-8 (CH₃)3P(BH₂P(C₆H₅)2)3BH₃ 

Relevant articles and documents

Synthesis and reactions of phosphine-methylsulfonyloxyborane complexes

Functionalizations of the boranato group of phosphine-boranes have been investigated. Trimethylphosphine-borane readily reacted with methanesulfonic acid in dichloromethane with evolution of hydrogen. The resulting trimethylphosphine-methylsulfonyloxyborane was subjected to nucleophilic substitution reaction on the boron atom with arenethiols or secondary phosphine-boranes in the presence of NaH. The reactivities of the substitution products obtained were also investigated. A new phosphine-borane having a P-B-P-B-P-BP-B bond linkage was synthesized.