1322588-73-7Relevant articles and documents
Toward the total synthesis of bryostatin 11: Stereoselective construction of the C13-exocyclic enoate in the C1-C16 fragment
Nakagawa-Goto, Kyoko,Crimmins, Michael T.
, p. 3032 - 3038 (2011/09/16)
We have utilized a spiroketal template in an approach to the C1-C16 fragment of bryostatin. The stereoselective construction of an exocyclic enoate at C13 and insertion of a vinyl group on C15 were accomplished by using Peterson-Yamamoto olefination and copper-catalyzed addition of vinyl magnesium bromide, respectively. Copyright