1322750-62-8

Basic information

• Product Name: (R,E)-1-(tert-butylsulfinyl)-2-styrylbenzene
• Synonyms: (R,E)-1-(tert-butylsulfinyl)-2-styrylbenzene
• CAS NO: 1322750-62-8
• Molecular Weight: 284.422
• Mol File: 1322750-62-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (R,E)-1-(tert-butylsulfinyl)-2-styrylbenzene(CAS DataBase Reference)
• NIST Chemistry Reference: (R,E)-1-(tert-butylsulfinyl)-2-styrylbenzene(1322750-62-8)
• EPA Substance Registry System: (R,E)-1-(tert-butylsulfinyl)-2-styrylbenzene(1322750-62-8)

Safety Data

• Hazardous Substances Data: 1322750-62-8(Hazardous Substances Data)

Upstream product

• 54737-45-0 (E)-2-bromostilbene 
• 1335243-47-4 C₁₁H₁₄O₂S 
• 773-47-7 dimethyl benzylphosphonate 
• 4170-71-2 (R)-(tert-butylsulfinyl)benzene 

Relevant articles and documents

Chiral sulfoxide-olefin ligands: Tunable stereoselectivity in Rh-catalyzed asymmetric 1,4-additions

A class of chiral sulfoxide-olefins were designed and synthesized through concise routes. Their applications as ligands in Hayashi-Miyaura reaction were studied, which found that vinyl substituents of the ligands vary in stereocontrolling ability. Particularly, either isomer of adducts with excellent ees could be readily obtained through changing the position of the substituents of olefins as well as changing the configuration of the CC bond of the ligands. Meanwhile, the substrate scope of arylboronic acids and alkenes was clearly shown.

A class of benzene backbone-based olefin-sulfoxide ligands for Rh-catalyzed enantioselective addition of arylboronic acids to enones

A class of readily available and easily tunable benzene backbone-based olefin-sulfoxide ligands was developed for the rhodium-catalyzed asymmetric conjugate addition reaction of arylboronic acids to enones with up to 97% yield and 97% ee.