13234-21-4Relevant articles and documents
Isomerization of olefins in the presence of reactive impurities
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, (2008/06/13)
A process and catalyst for isomerizing olefins are disclosed. The process and catalyst are particularly useful for isomerizing alkenyl bridged ring compounds to the corresponding alkyladiene bridged ring compounds. In one embodiment, the isomerization catalyst comprises an oxygen treated mixture of an alkali metal on a dried support having a surface area of 125 to 195 m2 /g when the support consists essentially of alumina wherein the alumina precursor is a large crystallite pseudoboehmite. The catalyst is particularly useful for isomerizing 5-vinyl-2-norbornene to 5-ethylidiene-2-norbornene. The catalyst is very active and highly selective and resistant to catalyst poisons. The process contacts the catalyst with an alkenyl bridged ring compound and yields the corresponding alkyladiene bridged ring compound.
Application of molecular dynamics to chromatographic-spectral identification of isomeric products of organic reactions
Zenkevich
, p. 1403 - 1409 (2007/10/03)
Isomeric products of [2+4]-cycloaddition reactions can be identified by gas chromatography-mass spectrometry on the basis of their experimental retention parameters and intramolecular vibrational and rotational energies (E) calculated by molecular mechanics for all possible isomers. The Chromatographic parameters change in the opposite direction with respect to E. The proposed approach allows unambiguous identification of four products formed by each of the reactions of butadiene with cyclopentadiene, of isoprene with 2,3-dimethylbutadiene, of cyclopentadiene with isoprene, and dimerization of isoprene and two of the four products formed by the reaction of 1,3-cyclohexadiene with cyclopentadiene. Both structural and steric isomers (exo, endo) can be distinguished. 1998 MAHK "Hayka/Interperiodica".
NEW POSSIBILITIES FOR CONTROL OF THE TRANSANNULAR CYCLIZATION OF 1,5-DIENES IN THE RITTER REACTION AS ILLUSTRATED BY METHYL-CIS-BICYCLONONA-3,7-DIENES
Nigmatova, V. B.,Andreev, V. A.,Pekhk, T. I.,Belikova, N. A.,Bobyleva, A. A.,et al.
, p. 2213 - 2223 (2007/10/02)
In the Ritter reaction 3-methyl and 3,4-dimethyl-cis-bicyclonona-3,7-dienes are converted either exclusively into acetylamines having the initial structure or into transannular cyclization products of the tricyclo3,7>nonane (brex