13235-90-0

Basic information

• Product Name: Silane, trichloro[2-(pentafluorophenyl)ethyl]-
• CAS NO: 13235-90-0
• Molecular Formula: C8H4Cl3F5Si
• Molecular Weight: 329.556
• Mol File: 13235-90-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Silane, trichloro[2-(pentafluorophenyl)ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, trichloro[2-(pentafluorophenyl)ethyl]-(13235-90-0)
• EPA Substance Registry System: Silane, trichloro[2-(pentafluorophenyl)ethyl]-(13235-90-0)

Safety Data

• Hazardous Substances Data: 13235-90-0(Hazardous Substances Data)

Upstream product

• 653-34-9 2,3,4,5,6-pentafluorostyrene 

Relevant articles and documents

THE REACTIONS OF HYDROSILANES WITH TRIFLUOROPROPENE AND PENTAFLUOROSTYRENE CATALYZED BY RUTHENIUM, RHODIUM AND PALLADIUM COMPLEXES

The reactions of hydrosilanes with trifluoropropene (TFP) and pentafluorostyrene (PFS) catalyzed by Ru3(CO)12 or RhCl(PPh3)3 give β-Rf-vinylsilane (1) and/or β-Rf-ethylsilane (2) (Rf=perfluorocarbon group).The 1/2 ratio is highly dependent on the nature of hydrosilane used.The ruthenium catalyst favors the formation of 1 compared with the rhodium catalyst.Neither α-Rf-vinylsilane nor α-Rf-ethylsilane was formed at all.Possible mechanisms which can accommodate characteristic features of these reactions are discussed.The hydrosilylation of TFP with dichloromethylsilane catalyzed by PdCl2(PhCN)2/2PPh3 gives the α-adduct (9a) exclusively, and this is transformed to the corresponding dialkoxysilanes, silane diol, oligosilane diols and cyclic oligosiloxanes.