132381-65-8

Basic information

• Product Name: Propanethioic acid, 2,2-dimethyl-, S-(4-methoxyphenyl) ester
• CAS NO: 132381-65-8
• Molecular Formula: C12H16O2S
• Molecular Weight: 224.324
• Mol File: 132381-65-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Propanethioic acid, 2,2-dimethyl-, S-(4-methoxyphenyl) ester(CAS DataBase Reference)
• NIST Chemistry Reference: Propanethioic acid, 2,2-dimethyl-, S-(4-methoxyphenyl) ester(132381-65-8)
• EPA Substance Registry System: Propanethioic acid, 2,2-dimethyl-, S-(4-methoxyphenyl) ester(132381-65-8)

Safety Data

• Hazardous Substances Data: 132381-65-8(Hazardous Substances Data)

Upstream product

• 696-63-9 4-Methoxybenzenethiol 
• 3282-30-2 pivaloyl chloride 
• 37170-49-3 trimethylsilyl 2,2-dimethylpropionate 
• 38325-58-5 4-methoxyphenyl trimethylsilyl sulfide 

Downstream Products

• 14248-23-8 methyl 3-(4-methoxyphenyl)-2,2-dimethylpropanoate 
• 1879-16-9 1-methoxy-4-methylsulfanyl-benzene 

Relevant articles and documents

Transition-metal-catalyzed regioselective aroyl- and trifluoro- acetylthiolation of alkynes using thioesters

Intermolecular CO-retained carbothiolation of alkynes using thioesters took place to afford β-SR substituted enone derivatives; the choice of catalyst (Pd(dba)2-dppe) and the introduction of a CF3 group into the thioesters are the key to achieving the transformation. The Royal Society of Chemistry 2009.

A New and Efficient Method for the Preparation of S-Phenyl Carbothioates via Mixed Anhydrides Using Active Titanium(IV) Salts

In the presence of a catalytic amount of titanium(IV) salt, various S-phenyl carbothioates are prepared in excallent yields by the reaction of nearly equimolar amounts of silyl derivatives of carboxylic acids and benzenethiols with p-trifluoromethylbenzoic anhydride.